Just to come back with some maths on why 1 bar doesn't work (I know you've abandoned the idea, but I got curious anyway and looked into it a bit more).
If you want a pressurized sphere (for the sake of the simplicity of the maths) of 200m3 volume (i.e. enough hydrogen to lift 200kg), then from v =(4/3) pi r3, we get a radius of 3.5m or about 23 feet diameter. That's pretty big.
Now, if you compare this with a party balloon of 10cm radius (which is on the limits of the tensile strength of rubber of that thickness). A party balloon is inflated to somewhere vaguely around 50cm H20 (had to look in a medical journal to figure this out - it comes from how hard you can blow!), which is roughly 5KPa. 1 bar is 100KPa. So you need your 10cm balloon to be 20 times thicker than a party balloon to withstand 1 bar - that's roughly twice as thick as an *uninflated* regular party balloon, so if you use rubber you need it to be around 10mm thick before inflation, and 1mm thick when inflated to withstand 1 bar. I'm not convinced thick rubber can stretch like that, but we'll ignore this for now.
Now that's for a 10cm radius balloon. A 3.5m radius rubber balloon must be 35 times thicker as tension is proportional to radius for a pressure vessel, so 35mm thick when inflated (or about 1.4 inches if you prefer old money).
How much would that weigh? Area of a sphere is 4 pi r2, so a 3.5m sphere has an area of 154 m2. Volume of rubber in a 3.5m sphere of 35mm thickness = 154* 0.035 = 5.4m3. Density of rubber is about 1500kg/m3, so the sphere would weigh 8100kg, or 8 tonnes. It won't fly, not even close.
So what can you do? As you scale up, the volume (and hence lifting capability) grows with r3. The area of the balloon grows with r2. The thickness needs to grow with r for the same pressure. So the mass of the balloon grows with r3. Basically you can't win by making it bigger.
Your only hope is to go with something that has a lot better tensile strength than rubber, but which is also light. Rubber has a tensile strength of around 15MPa according to wikipedia. Nylon is about 5 times better, but you'd still need a 7mm thick envelope. Nylon is also slightly less dense, but it would still weight 1.2 tonnes. Still not useful
The only thing I can think of that might work is carbon fibre. According to wikipedia (source of all truth :-) carbon fibre has a tensile strength of 5600MPa. But I've also seen sources say 1500MPa, and most places say three times stronger than steel, so I'm inclined to believe 1500. But you've got to have the fibres aligned both ways for an envelope, so the effective tensile strength would be halved. So now you could decrease the thickness by a factor of 750/15 = 50. This gives an envelope of 0.7mm. But would it fly? Carbon fibre is slightly denser than rubber 1700 vs 1500, so this gives an envelope mass of 154*0.0007*1700 = 183kg. It would
fly, but it wouldn't lift you.
Caveats: all this is from extrapolation from a party balloon, based on some pretty shakey numbers :-) But unless I messed up the maths (entirely likely!), it makes it pretty clear why airships aren't pressurised to anything significant above atmospheric.